Novel Triazine Schiff Base-Based Cationic Gemini Surfactants: Synthesis and Their Evaluation as Antiwear, Antifriction, and Anticorrosive Additives in Polyol

Two novel triazine Schiff base-based cationic gemini surfactants namely N,N′-bis{(p-(N,N,N-tetradecyldimethylammonium bromide)benzylidene} 6-methyl-1,3,5-triazine-2,4-diamine (14-MTR-14) and N,N′-bis{(p-(N,N,N-tetradecyldimethylammonium bromide)benzylidene} 6-phenyl-1,3,5-triazine-2,4-diamine (14-PTR-14) were synthesized following the two-step reaction. First the intermediate adduct was synthesized by reaction of the 4-(dimethylamino)benzaldehyde with 1-bromotetradecane. In the second step, the germinal surfactants 14-MTR-14 and 14-PTR-14 were synthesized by imine coupling with this intermediate adduct with 6-methyl-1,3,5-triazine-2,4-diamine and 6-phenyl-1,3,5-triazine-2,4-diamine, respectively. Both were characterized using elemental analysis (CHN), infrared (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and thermogravimetry (TG). The compounds were then evaluated as anticorrosive and lubricity improver additive in polyol lube base oil. Both the surfactants show the similar anticorros...