Unusual Atmospheric Water Trapping and Water InducedReversible Restacking of 2D Gallium Sulfide Layers in NaGaS 2 Formed by Supertetrahedral Building Unit

Amit Adhikary,Hooman Yaghoobnejad Asl,Prashanth Sandineni,Srikanth Balijapelly,Sudip Mohapatra,Sajal Khatua,Sanjit Konar,Nikolay Gerasimchuk,Aleksandr V. Chernatynskiy,Amitava Choudhury

Unusual Atmospheric Water Trapping and Water InducedReversible Restacking of 2D Gallium Sulfide Layers in NaGaS 2 Formed by Supertetrahedral Building Unit

2020

Amit Adhikary
Hooman Yaghoobnejad Asl
Prashanth Sandineni
Srikanth Balijapelly
Sudip Mohapatra
Sajal Khatua
Sanjit Konar
Nikolay Gerasimchuk
Aleksandr V. Chernatynskiy
Amitava Choudhury

Two new ternary materials NaGaS2 (1) and Fe-doped phase of NaGaS2, NaFe0.135Ga0.865S2 (2) have been synthesized by employing polysulfide flux. Single crystal XRD analysis of 1 and 2 show that the s...

Keywords:

X-ray photoelectron spectroscopy
Materials science
Ternary operation
Flux
Single crystal
Trapping
Fourier transform infrared spectroscopy
Polysulfide
building unit
Inorganic chemistry

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