Orbital Phase Perspective of Goodenough-Kanamori-Anderson Rules (GKA Rules) in Superexchange Interaction
2020
Goodenough-Kanamori-Anderson
rules (GKA rules) in superexchange interaction discriminate
the magnetic properties of two magnetic metal ions bridged with an anion. We
propose here that the GKA rules can be explained in
terms of the orbital phase continuity-discontinuity property of cyclic orbital
interaction including direct metal-metal orbital interaction.
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