Thermodynamic Interaction Parameters for Bulk and Nano Copper Acetate, CuAc with (CPB) * in Mixed Acetone (Ac) - H 2 O Solvents

Characterization of nano copper acetate, CuAc, Cu(OAc) 2 is done by transmission electron microscope (TEM), atomic force microscope( AFM) and x-ray diffraction. The thermodynamic parameters for association and complex formation for both bulk Cu(OAc) 2 (normal) and nano Cu(OAc) 2 were evaluated by using condutometric measurements. The association thermodynamic parameters of both bulk [CuAc], Cu(OAc) 2 and nano-Cu(OAc) 2 salts in acetone (Ac)+H 2O were calculated in presence of N - bezylidene-4-chlorobenzohydrazide(CPB), nonisothermally at different temperatures, 293.15, 298.15, 303.15 and 308.15K. The thermodynamic solvation parameters for both types of Cu(OAc) 2[CuAc] were compared.