Buckling analysis and control of layered electrode structure at finite deformation

Abstract This work has proposed a coupled mechanochemical model to investigate the buckling performance of electrode and thereby enhance the mechanical integrity of lithium-ion batteries. This method based upon finite deformation theory is capable to simulate the state of charge ( SOC ) and path dependent buckling phenomenon of the layered structure. It is revealed that the buckling behavior of an electrochemical loaded electrode depends not only on the material properties and the electrode geometry but also on the charging/discharging process, SOC as well as the operation current rate. Moreover, with regarding to the lithiation stiffening active material, the results show that increasing the current density in lithiation while decreasing it upon delithiation can increase the relatively critical buckling load, and contribute the electrode to withstand buckling failure. As for the lithiation softening one, it is disclosed that the bucking resistance would be impaired in lithiation and recovered upon full delithiation. In addition, to eliminate the adverse effect of lithiation soften on the electrode buckling resistance, design insights into the current collector have been provided.