Enantioselective Wacker-Type Cyclization of 2-Alkenyl-1,3-diketones Promoted by Pd-SPRIX Catalyst.

Kazuhiro Takenaka,Suman C. Mohanta,Mahesh L. Patil,C.V. Laxman Rao,Shinobu Takizawa,Takeyuki Suzuki,Hiroaki Sasai

Enantioselective Wacker-Type Cyclization of 2-Alkenyl-1,3-diketones Promoted by Pd-SPRIX Catalyst.

2010

Kazuhiro Takenaka
Suman C. Mohanta
Mahesh L. Patil
C.V. Laxman Rao
Shinobu Takizawa
Takeyuki Suzuki
Hiroaki Sasai

An enantioselective intramolecular Wacker-type cyclization of 2-alkenyl-1,3-diketones catalyzed by a Pd(II)−SPRIX complex was developed. The reaction proceeded in a 6-endo-trig mode to give the des...

Keywords:

Enantioselective synthesis
Catalysis
Organic chemistry
Chemistry

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