Cyclic allylic carbonates as a renewable platform for protecting chemistry in water
2018
The present work explores different cyclic allylic carbonates as a potential class of allylcarbamate precursors. The 5-membered carbonate formed a carbamate with very good thermal and pH stability, which could be cleanly deprotected in aqueous solution, in just 30 min with 2 mol% Pd(OAc)2 as catalyst. The polar nature of the installed motif made it possible to deprotect highly unpolar substrates in water as solvent.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
73
References
0
Citations
NaN
KQI