Ultralow thermal conductivity in tetrahydrofuran clathrate hydrate

The detailed knowledge of the low thermal conductivity of host–guest compounds is essential to improve our fundamental understanding of heat conduction in complex solids and develop high-performance thermoelectric materials. In this Letter, the intrinsic ultralow thermal conductivity (0.44 ± 0.06 W m−1 K−1 in 140–190 K) of the tetrahydrofuran (THF) clathrate hydrate is characterized by the time-domain thermoreflectance technique. The underlying heat conduction mechanism is further investigated by non-equilibrium molecular dynamics simulations. We find that trapped THF molecules do harmonic motions and behave as parts of a crystalline structure, thus playing negligible roles in thermal conductivity reduction. The large unit cell and complex cage-like host structure dominate the low thermal conductivity of the THF hydrate.