Hydride-induced cleavage of C–O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application

Qifeng Wang,Lantao Liu,Chen Lin,Hui Sun,Wen-Xiong Zhang,Zhenfeng Xi

Hydride-induced cleavage of C–O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application

2009

Qifeng Wang
Lantao Liu
Chen Lin
Hui Sun
Wen-Xiong Zhang
Zhenfeng Xi

Hydride-induced cleavage of the C–O bond in the pyran ring followed by ring closure of unsaturated acylmetalates and reductive elimination was achieved.

Keywords:

Cleavage (embryo)
Reductive elimination
Hydride
Photochemistry
Pyran
Inorganic chemistry
Carbene
Chemistry

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