A Digallane Gold Complex with a 12-Electron Auride Center: Synthesis and Computational Studies

Kohei Susukida,Leonardo I. Lugo-Fuentes,Shozo Matsumae,Kazuki Nakanishi,Masaaki Nakamoto,Yohsuke Yamamoto,Rong Shang,Joaquín Barroso-Flores,J. Oscar C. Jiménez-Halla

A Digallane Gold Complex with a 12-Electron Auride Center: Synthesis and Computational Studies

2020

Kohei Susukida
Leonardo I. Lugo-Fuentes
Shozo Matsumae
Kazuki Nakanishi
Masaaki Nakamoto
Yohsuke Yamamoto
Rong Shang
Joaquín Barroso-Flores
J. Oscar C. Jiménez-Halla

The reaction of Power’s digalladeltacyclane with Au(PPh3)Cl led to formation of a digallium gold complex (2) with both chloride and gold bridging between two gallium atoms. The bonding parameters f...

Keywords:

Electron
Digallane
Gallium
Chemistry
Crystallography
Atom
Chloride

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