Acrylato[tris-(1-methyl-benzimidazol-2-ylmeth-yl)amine]zinc(II) perchlorate-dimethyl-formamide-methanol (1/1/1.5) at 153 (2) K.

2008 
In the title complex, [Zn(C3H3O2)(C27H27N7)](ClO4)·C3H7NO·1.5CH4O, the ZnII ion is five-coordinated by four N atoms from a tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from an acrylate ligand in a distorted trigonalbipyramidal geometry with approximate mol­ecular C3 symmetry. The atoms of the acrylate ligand are disordered over two sites, with approximate occupancies of 0.84 and 0.16. In addition, a methanol solvent mol­ecule is disordered over two sites with equal occupancies. In the crystal structure, the full-occupancy methanol is linked to a dimethyl­formamide mol­ecule by an inter­molecular O—H⋯O hydrogen bond.
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