The Nickel isotope composition of the authigenic sink and the diagenetic flux in modern oceans

Abstract We investigated Ni isotopes in a stratigraphic sequence of pelagic clays collected during ODP core leg 185 on site 1149 in Western Pacific Ocean near the Izu-Bonin subduction trench in order to determine the Ni isotope composition of the authigenic Mn-oxides sink and evaluate the composition of the diagenetic Ni input flux. This predominant oxic sink likely controls the Ni isotope budget in modern oceans. The sequence presented here is a 170 m-thick sequence of pelagic sediments deposited on some of the oldest oceanic crust of the seafloor, and the base was dated at 104 Ma. Nickel isotope values (δ60/58Ni relative to NIST SRM 986) vary in the range of 0.04 ± 0.04 to 1.03 ± 0.03‰. There is a trend between depth in the stratigraphic sequence and increasing Mn/Fe, Mn/Al, higher Ni concentration and heavier Ni isotope values. This trend is accounted for by authigenic Mn-oxyhdroxides precipitation in the sediment and scavenging of dissolved metals in the sediment porewaters. This indicates that authigenic oxide minerals in deep-sea pelagic clays are a relevant sink for Ni in modern oceans. Results enable us to determine the authigenic oxic output flux of 3.58 × 108 mol/yr of Ni with a Ni isotope composition of 1.2‰, this oxic output is ~0.4‰ lighter than the oxic output flux in Fe Mn crusts and nodules. This study shows that Ni isotope variations along the stratigraphic sequence could be the result of mixing between a pure pelagic clays end-member at ~0.1‰ and a pure Mn-oxyhydroxides end-member at ~1.2‰. We suggest that to keep the system at steady-state conditions the oxic output flux is compensated for by a diagenetic input flux of 3.7 × 108 mol/yr which is characterized by a highly fractionated Ni isotope composition of ~2.9‰.