Critical charge fluctuations and quantum coherent state in excitonic insulator Ta$_2$NiSe$_5$.

2020 
Attraction between electrons in metals drives superconductivity - an example of a macroscopic coherent state. In semiconductors, electrons and holes may sustain macroscopic coherence due to Coulomb attraction in another state - the excitonic insulator. With only a few candidate materials known, many of its features can be obscured by structural effects, making the excitonic insulator state challenging to identify. Using polarization-resolved Raman spectroscopy, we reveal critical softening of an excitonic collective mode driving the transition in Ta$_2$NiSe$_5$, and coherent superposition of band states at the gap edge, analogous to coherence factors in a superconductor. The temperature evolution of the spectra reveals departures from mean-field theory predictions, pointing to a unified view of Ta$_2$NiSe$_5$ as a strongly correlated excitonic insulator.
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