Polar order of 0.67BiFeO3-0.33BaTiO3 near the morphotropic phase boundary

In this work, the symmetric studies on the structure-property of the unpoled and poled states of 0.67BiFeO3-0.33BaTiO3 (0.67BF-0.33BT) were carried out in order to examine the existing unclear issues over the origin for the morphotropic phase boundary (MPB) of BF-BT.The typical relaxor-like anomaly was observed, giving a freezing temperature of 627 K. The remnant polarization (Pr) and maximum value of electro-strain (Sm) increase clearly on heating (Pr, 40 uC/cm2; Sm, 0.191 % under 40 kV/cm at 453 K). The first-cycle electro-strain loops at 298 K and 453 K suggest the similarity between 0.67BF-0.33BT and normal ferroelectrics. Both the unpoled and poled samples show the similar frequency dispersion. Unlike Bi1/2Na1/2TiO3-based ceramics, the temperature dependence of relative permittivity for the poled sample does not show any evidence related to the changes between the ergodic relaxor state and ferroelectric-like state. Supported by the Rietveld refinement of XRD patterns, bright-field images and selected-area electron diffractions SAED, our studies demonstrated that the long-range ferroelectric domains is absent by poling. Both the unpoled and poled state could be well understood by the ferroelectric state with the nanodomains. We believe that this work is helpful for the further understanding of the MPB in BF-BT.