CHAOS IV: Gas-Phase Abundance Trends From The First Four CHAOS Galaxies.

The chemical abundances of spiral galaxies, as probed by HII regions across their disks, are key to understanding the evolution of galaxies over a wide range of environments. We present LBT/MODS spectra of 52 HII regions in NGC3184 as part of the CHemical Abundances Of Spirals (CHAOS) project. We explore the direct-method gas-phase abundance trends for the first four CHAOS galaxies, using temperature measurements from one or more auroral line detections in 190 individual HII regions. We find the dispersion in Te-Te relationships is dependent on ionization, as characterized by F_5007/F_3727, and so recommend ionization-based temperature priorities for abundance calculations. We confirm our previous results that [NII] and [SIII] provide the most robust measures of electron temperature in low-ionization zones, while [OIII] provides reliable electron temperatures in high-ionization nebula. We measure relative and absolute abundances for O, N, S, Ar, and Ne. The four CHAOS galaxies marginally conform with a universal O/H gradient, as found by empirical IFU studies when plotted relative to effective radius. However, after adjusting for vertical offsets, we find a tight universal N/O gradient of alpha_N/O = -0.33 dex/Re with sigma_tot. = 0.08 for Rg/Re < 2.0, where N is dominated by secondary production. Despite this tight universal N/O gradient, the scatter in the N/O-O/H relationship is significant. Interestingly, the scatter is similar when N/O is plotted relative to O/H or S/H. The observable ionic states of S probe lower ionization and excitation energies than O, which might be more appropriate for characterizing abundances in metal-rich HII regions.