Topochemical anion insertion into one-dimensional Bi channels in Bi2PdO4

Fumitaka Takeiri,Takeshi Yajima,Saburo Hosokawa,Yoshitaka Matsushita,Hiroshi Kageyama

Topochemical anion insertion into one-dimensional Bi channels in Bi2PdO4

2020

Fumitaka Takeiri
Takeshi Yajima
Saburo Hosokawa
Yoshitaka Matsushita
Hiroshi Kageyama

Abstract We show anion intercalation reaction to ternary palladate Bi2PdO4 (P4/ncc) with one-dimensional (1D) channels comprised of Bi3+ ions. By low-temperature treatment with XeF2, fluoride anions are inserted in the 1D pores (4b site), giving Bi2PdO4Fx (x

Keywords:

Ion
Crystallography
Chemistry
Fluoride
Ternary operation
anion intercalation

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