Chemo- and Stereospecific Solid-State Thermal Dimerization of Sodium trans-2-Butenoate and γ-Ray-Induced Single-Crystal-to-Single-Crystal Dimerization of Hexaaquamagnesium trans-2-Butenoate Dihydrate: Both Give rel-(3S,4R)-1-Hexene-3,4-dicarboxylate but by Different Mechanisms. Stereospecific γ-Ray-Induced Trimerization of Sodium trans-2-Butenoate

Wen Shang,Roxana F. Schlam,Magali B. Hickey,Jingye Zhou,Kraig A. Wheeler,Graciela Díaz de Delgado,Chun-Hsing Chen,Barry B. Snider,Bruce M. Foxman

Chemo- and Stereospecific Solid-State Thermal Dimerization of Sodium trans-2-Butenoate and γ-Ray-Induced Single-Crystal-to-Single-Crystal Dimerization of Hexaaquamagnesium trans-2-Butenoate Dihydrate: Both Give rel-(3S,4R)-1-Hexene-3,4-dicarboxylate but by Different Mechanisms. Stereospecific γ-Ray-Induced Trimerization of Sodium trans-2-Butenoate

2020

Wen Shang
Roxana F. Schlam
Magali B. Hickey
Jingye Zhou
Kraig A. Wheeler
Graciela Díaz de Delgado
Chun-Hsing Chen
Barry B. Snider
Bruce M. Foxman

γ-Irradiation of crystalline hexaaquamagnesium trans-2-butenoate dihydrate affords rel-(3S,4R)-1-hexene-3,4-dicarboxylate by a single-crystal-to-single-crystal reaction. The reaction proceeds by a ...

Keywords:

Single crystal
Chemistry
Crystallography
Stereospecificity
Sodium
1-Hexene
Solid-state

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