Biomimetic Radical Chemistry of Iron and Copper: Hemes, Iron-Sulfur Clusters, and Alkoxides
2014
Iron and copper centers typically undergo one-electron redox changes while mediating biochemical processes. Presented here will be new reactions in which Fe or Cu redox change is coupled to bond-making/bond-breaking, including metal-oxygen bonds and oxygen-hydrogen of sulfur-hydrogen bonds in a ligand.
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