Synthesis of the individual regioisomer of the bisadduct of fullerene C60 with tert-butyl 11-azido-3,6,9-trioxaundecanoate

Irina P. Romanova,G. G. Yusupova,A. A. Balandina,Sh. K. Latypov,Dmitry G. Yakhvarov,Nikolay E. Nifant’ev,D. V. Yashunskii,O. G. Sinyashina

Synthesis of the individual regioisomer of the bisadduct of fullerene C60 with tert-butyl 11-azido-3,6,9-trioxaundecanoate

2007

Irina P. Romanova
G. G. Yusupova
A. A. Balandina
Sh. K. Latypov
Dmitry G. Yakhvarov
Nikolay E. Nifant’ev
D. V. Yashunskii
O. G. Sinyashina

At 130 °C the reaction of fullerene C60 with 1-azido-9-tert-butoxycarbonyl-3,6,9-trioxanonane occurs regioselectively affording one regioisomer of the bisadduct.

Keywords:

Fullerene
Structural isomer
Organic chemistry
Chemistry
tert butyl

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