Phosphine–Nickel Complex Catalyzed Cross‐Coupling of Grignard Reagents with Aryl and Alkenyl Halides: 1,2‐Dibutylbenzene

Phosphine–nickel complex catalyzed cross-coupling of Grignard reagents with aryl and alkenyl halides: 1,2-Dibutylbenzene byproduct: 1-butyl-2-chlorobenzene product: 1,2-dibutylbenzene product: C6H5C4H9 product: 1,3-[1,3-[(CH3)3SiCH2]2C6H4 product: (CH3)2CH- and CH3(CH2)2C6H5 product: (S)-(+)-C6H5CH(CH3)CHCH2 product: (Z)-C6H5CHCHC6H5 product: (Z)-C6H5CHCHC6H5 product: 4-ClC6H4CHCH2 product: α-C10H7C(CH3)CH2 Keywords: coupling; Grignard and related reactions; metal-catalyzed reactions, nickel; butylmagnesium bromide, preparation of; dichloro[1,3-bis(diphenylphosphino)propane]nickel(II), preparation of; diethyl ether