Magnetocurrent of Charge-Polarizable C60-Diphenylaminofluorene Monoadduct-Derived Magnetic Nanocomposites
2012
We demonstrated the strategy of a nanocomposite design by the incorporation of both a delocalized π-electrons system in a closely bound acceptor–donor analogue chromophore, based on charge-polarizable C60(>DPAF-C9) nanostructure 1, and spin-polarized d-electrons in the form of γ-FeOx nanoparticles. Facile intramolecular electron transfer from the DPAF-C9 donor moiety to the C60 acceptor cage of 1 upon activation to the excited state with a long lifetime of the charge-separated state forms a possible mechanism to integrate semiconducting and magnetic properties in a single system. We observed an appreciable magnetocurrent (MC) of C60(>DPAF-C9)-encapsulated magnetic γ-FeOx nanoparticles in PMMA matrix upon applying a magnetic field from 0 to 300 mT at either 77 K (12% MC) or 300 K (4.5% MC). Interestingly, the detailed analysis of magnetocurrent curve profiles taken at 77 K allowed us to conclude that the measured magnetocurrent may be attributed to the contributions from magnetic field-dependent excited-st...
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