Breaking the symmetry: C1-salans with (N–H) backbones
2021
We disclose a synthetic route that providess an unprecedented library of C1 salan ligands endowed with (N–H) backbones, previously limited to N-methylated backbones. Efforts to identify a generic complexation protocol to yield the corresponding Cu(II)–salan complexes demonstrate the scope and limitations of this approach.
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