Analysis of solid‐state luminescence emission amplification at substituted anthracenes by host‐guest complex formation

Small robust organic molecules showing solid-state luminescence are promising candidates for optoelectronic materials. Herein, we investigate a series of diphenylphosphanyl anthracenes [9-PPh 2 -10-R-(C 14 H 8 )] and their sulfur oxidised analogues. The oxidation causes drastic changes in the molecular structure as the new orientation of the bulky (S)PPh 2 substituent induces a strong butterfly bent structure of the anthracene core, which triggers a strong bathochromic shift resulting in a green solid-state fluorescence. As the emission properties change only slightly upon aggregation the origin of the emission is attributed to a typical monomer fluorescence. The host-guest complexes of [9-(S)PPh 2 -10-Ethyl-(C 14 H 8 )] with four basic arenes reveal an emission enhancement up to five-times higher quantum yields compared to the pure host. Less interchromophoric interactions and a restriction of intramolecular motion within the host molecules due to fixation by weak C-H···π interactions with the co-crystallised arene are responsible for that emission enhancement.