Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution.

Ayaka Yubuta,Tomoka Hosokawa,Masayuki Gon,Kazuo Tanaka,Yoshiki Chujo,Akihiro Tsurusaki,Ken Kamikawa

Enantioselective Synthesis of Triple Helicenes by Cross-Cyclotrimerization of a Helicenyl Aryne and Alkynes via Dynamic Kinetic Resolution.

2020

Ayaka Yubuta
Tomoka Hosokawa
Masayuki Gon
Kazuo Tanaka
Yoshiki Chujo
Akihiro Tsurusaki
Ken Kamikawa

Optically active triple helicenes (TH-1) were prepared via a palladium-catalyzed enantioselective cross-cyclotrimerization of two helicenyl arynes 5, which are generated in situ from 3, with dialky...

Keywords:

In situ
Enantioselective synthesis
Organic chemistry
Kinetic resolution
Combinatorial chemistry
optically active
Chemistry
Aryne

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