Organocatalytic Oxidative Dimerization of Alcohols to Esters
2012
2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1–2 mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55–99%.
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