Anisotropic microcrystalline powder alignment of the weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = Pr, Nd, Sm, Eu, Gd, Gd0.5Dy0.5)

The powder alignment method is used to investigate the anisotropic physical properties of the weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = Pr, Nd, Sm, Eu, Gd, Gd0.5Dy0.5). Due to weak magnetic anisotropy of this tetragonal system, partially c-axis aligned microcrystalline powder (diameter ~ 1?10 ?m) in epoxy can be obtained only for R = Eu and Gd through the field-rotation powder alignment method where c-axis is perpendicular to the aligned magnetic field Ba = 0.9 T and parallel to the rotation axis. For smaller rare earth compound R = Gd0.5Dy0.5, powder alignment can be achieved using the simple field powder alignment method where c-axis is partially aligned along the aligned magnetic field. No powder alignment can be achieved for larger rare earths R = Pr, Nd or Sm due to the lack of magnetic anisotropy in these compounds. The mechanism of powder alignment at room temperature using the spin-orbital-related anisotropic paramagnetic susceptibility and the low temperature anisotropic physical properties of RuSr2EuCu2O8 is discussed.