Stereoselective allylic 1,3-dienylation of Morita–Baylis–Hillman carbonates via an alkylation–denitration sequence

Lin Jiang,Liu-Dong Yu,Pei-Ying Peng,Hongli Li,Jiang Dengbang,Yi-Dan Wang,Minglong Yuan,Mingwei Yuan

Stereoselective allylic 1,3-dienylation of Morita–Baylis–Hillman carbonates via an alkylation–denitration sequence

2020

Lin Jiang
Liu-Dong Yu
Pei-Ying Peng
Hongli Li
Jiang Dengbang
Yi-Dan Wang
Minglong Yuan
Mingwei Yuan

A two-step, metal-free process for stereoselective allylic 1,3-dienylation of Morita–Baylis–Hillman (MBH) carbonates under mild reaction conditions has been developed. Using cyclic allylic nitro co...

Keywords:

Medicinal chemistry
Chemistry
Tsuji–Trost reaction
Alkylation
Allylic rearrangement
Stereoselectivity
reaction conditions
Nitro

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