Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN2){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ3O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1)
2017
In the title compound, [Co(C11H12NO6P)(C6H5N3)2]·C6H5N3, the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianion N,O,O′,O′′-chelates the CoII cation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the CoII cation to complete the slightly distorted octahedral coordination. In the crystal, classical O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.
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