Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand

We present two important trends in the reactivity of the titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (MeNacNac– = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph) with nucleophilic reagents RLi (R...