Effect of Nanopowders (TiO2 and MMT) and Aramid Honeycomb Core on Ablative, Thermal and Dynamic Mechanical Properties of Epoxy Composites

Abstract The present work investigates the ablative, thermal and dynamic mechanical properties of epoxy resin modified with nano-titanium dioxide and organomodified monmorillonite. The composites properties with aramid honeycomb core as stiffness reinforcement were compared with those without honeycomb. Samples have been subjected to combustions gases at a temperature above 1900°C during 120 seconds. The best thermal protective properties, i.e. the lowest: temperature of the rear surface area and ablative weight loss were exhibited by the composites containing 3.75% of oMMT and 1.25% of TiO2 with aramid honeycomb core. Dynamic mechanical thermal analyser measurements were carried out on an Instrument DMA SDTA861. The tests were performed by using a compression deformation mode in the temperature range from 20°C to 140°C. The glass transition temperature (Tg) was determined from the position of the maximum value of tan δ. This temperature reached values from about 74°C (with tan δ = 0,59) to 79°C (for tan δ = 0,66). The highest values of the complex modulus M* were in the range from 70 MPa to 465 MPa, for all phase compositions, but at temperature of 140°C the complex modulus M* had much lower values in the range of 20-25 MPa.