Sparkling nights and very hot days on WASP-18b: the formation of clouds and the emergence of an ionosphere.

WASP-18b is an utra-hot Jupiter with a temperature difference of upto 2500K between day and night. Such giant planets begin to emerge as planetary laboratory for understanding cloud formation and gas chemistry in well-tested parameter regimes in order to better understand planetary mass loss and for linking observed element ratios to planet formation and evolution. We aim to understand where clouds form, their interaction with the gas phase chemistry through depletion and enrichment, the ionisation of the atmospheric gas and the possible emergence of an ionosphere on ultra-hot Jupiters. We utilize 1D profiles from a 3D atmosphere simulations for WASP-18b as input for kinetic cloud formation and gas-phase chemical equilibrium calculations. We solve our kinetic cloud formation model for these 1D profiles that sample the atmosphere of WASP-18b at 16 different locations along the equator and in the mid-latitudes and derive consistently the gas-phase composition. The dayside of WASP-18b emerges as completely cloud-free due to the very high atmospheric temperatures. In contrast, the nightside is covered in geometrically extended and chemically heterogeneous clouds with disperse particle size distributions. The atmospheric C/O increases to $>0.7$ and the enrichment of the atmospheric gas with cloud particles is $\rho_{\rm d}/\rho_{\rm gas}>10^{-3}$. The clouds that form at the limbs appear located farther inside the atmosphere and they are the least extended. Not all day-night terminator regions form clouds. The gas-phase is dominated by H$_2$, CO, SiO, H$_2$O, H$_2$S, CH$_4$, SiS. In addition, the dayside has a substantial degree of ionisation due to ions like Na$^+$, K$^+$, Ca$^+$, Fe$^+$. Al$^+$ and Ti$^+$ are the most abundant of their element classes. We find that WASP-18b, as one example for ultra-hot Jupiters, develops an ionosphere on the dayside.