Evidence for Multiband Superconductivity and Strong Electronic Correlation in Zr$_5$Pt$_3$C$_x$ Compounds

The physical properties of the Zr$_5$Pt$_3$ compound with C interstitial doping in hexagonal D88 crystalline structure was investigated. Results show significant differences in the x-ray photoelectron spectra related to the Pt orbitals, with 5d-3d hybridizations, indicating a possible new group of superconductors. This becomes evident from examination of the previously unreported signature of unconventional superconductivity and stronger electronic correlations in Zr$_5$Pt$_3$C$_x$ compounds. Macroscopic measurements as specific heat at low temperature reveal a bulk superconducting transition close to 7 K with very high electronic contribution, which corroborates with the expressive value of calculated density state. In fact, signatures of unconventional superconductivity are observed for lower and upper critical field diagrams. The anomalous electrical resistivity is observed in the normal state with signatures of strong electron-electron interaction. Calculations of the electronic structure of Zr$_5$Pt$_3$ show a complex Fermi surface with high density of states.