Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes

Takanori Iwasaki,Toshikazu Akaiwa,Yuko Hirooka,Shrinwantu Pal,Kyoko Nozaki,Nobuaki Kambe

Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes

2020

Takanori Iwasaki
Toshikazu Akaiwa
Yuko Hirooka
Shrinwantu Pal
Kyoko Nozaki
Nobuaki Kambe

Lithium diphenyliridate complexes bearing cycloocta-1,5-diene (COD) as a ligand were synthesized by treating [IrCl(cod)]2 with phenyllithium and subsequent recrystallization. X-ray crystallographic...

Keywords:

Crystallography
Recrystallization (chemistry)
Chemistry
Phenyllithium
Solvent
Ligand
Lithium
ion pairs

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