Superatom spin-state dynamics of structurally precise metal monolayer-protected clusters (MPCs)
2019
Electronic spin-state dynamics were studied for a series of Au25(SC8H9)18q and Au24Pd(SC8H9)18 monolayer-protected clusters (MPCs) prepared in a series of oxidation states, q, including q = −1, 0, +1. These clusters were chosen for study because Au25(SC8H9)18−1 is a closed-shell superatomic cluster, but Au25(SC8H9)180 is an open-shell (7-electron) system; Au25(SC8H9)18+1 and PdAu24(SC8H9)180 are isoelectronic (6-electron) closed-shell systems. Carrier dynamics for electronic fine structure spin states were isolated using femtosecond time-resolved circularly polarized transient-absorption spectroscopy (fs-CPTA). Excitation energies of 1.82 eV and 1.97 eV were chosen for these measurements on Au25(SC8H9)180 in order to achieve resonance matching with electronic fine structure transitions within the superatomic P- and D-orbital manifolds; 1.82-eV excited an unpaired Pz electron to D states, whereas 1.97-eV was resonant with transitions between filled Px and Py subshells and higher-energy D orbitals. fs-CPTA ...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
45
References
7
Citations
NaN
KQI