Influence of heat treatments on residual tritium amount in tritiated stainless steel waste

Abstract In the framework of waste management strategy for future fusion reactor, it has been demonstrated that one of the major issue is to reduce the high level waste. The tritium activity strongly contributes to the waste classification. A better knowledge of the mechanisms involved in tritium trapping and desorption will allow to choose the most appropriate procedure to reduce the tritium constraint. This paper deals with the management of tritiated steels and the way to reduce tritium transfer. This experimental work concerns steel obtained by remelting under vacuum of tritiated austenitic stainless steel wastes. The goal of this study is to develop heat treatments in solid phase to lower the residual tritium concentration and its desorption kinetics at room temperature. The surface activity, the desorption of residual tritium at room temperature and the residual concentration have been measured for each condition (temperature, time, atmosphere, etc.). For reheating temperatures below 600 °C, the surface activity increases by one or two orders of magnitude; this is the consequence of the formation of a tritium rich oxide layer. After a 20 h annealing above 300 °C and removing of the tritium rich oxide layer, the surface activity is strongly reduced (80%) when compared with the value measured before annealing. For such annealing conditions, the amount of desorbed tritium is reduced by a factor 25 and the desorption kinetics yield a reduction factor of 40–50 after annealing at 400 °C for 20 h.