Towards pyrrhotite/magnetite geothermometry in low-grade metamorphic carbonates of the Tethyan Himalayas (Shiar Khola, Central Nepal)

2002 
Abstract In Mesozoic metacarbonates of the Tethyan Himalayas (Shiar Khola area, Central Nepal) two characteristic remanent magnetisations (ChRM 1 and ChRM 2 ) were identified by their unblocking temperature spectra. The ChRM 1 is carried by pyrrhotite (unblocking temperature: 270–360°C) and the ChRM 2 by magnetite (unblocking temperature spectra: 430–580°C). The temperature-related formation of pyrrhotite at the expense of primary magnetite during low-grade metamorphism in marly carbonates allows the determination of thermal gradients by the pyrrhotite/magnetite ratio. This new method can be used as a geothermometer for T ≤300°C in low-grade metamorphic carbonates, where other methods are not available. This method is applied for the first time in the Tethyan Himalayas of Central Nepal. In the Shiar Khola valley, systematic variations in the ferrimagnetic content of the metacarbonates along an E–W profile were detected by the ratio of remanence intensity of pyrrhotite to magnetite, derived from natural remanent magnetisation ( R PYR/MAG ) and saturation magnetisation ( S PYR/MAG ). Over a stretch of 10 km the R PYR/MAG and S PYR/MAG increase from W to E from ~0.42 to ~0.91 and ~0.48 to ~1.0, respectively. Based on temperature estimates, the eastern part experienced upper anchizone–epizone (~250–300°C) conditions, while the western part underwent only diagenesis (~200°C). The temperature gradient and the temperature ranges suggested are consistent with the findings of the calcite twin lamellae geothermometry which is a non-magnetic method.
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