A New Four‐Arm Organosiloxane with Thermopolymerizable Trifluorovinyl ether Groups: Synthesis and Conversion to the Polymer with both Low Dielectric Constant and Low Water Uptake

A new fluoro-containing four-arm organosiloxane has been successfully synthesized, which can be easily converted to a cross-linked network, showing water uptake of below 0.12 wt% (maintained in boiling water for 72 h) and dielectric constant of below 2.56 with dissipation factor of near 1.8 × 10−3 at 30 MHz, as well as showing high transparency and good thermostability. These data indicate that this new organosiloxane is suitable as an adhesive or sealant for the applications in microelectronic industry.