Reactions of Amidinate-Supported Silylene with Organoboron Dihalides.

The silicon atom in LSiCl or LSiMes (L = PhC(NtBu)2, Mes = 2,4,6-Me3C6H2) inserts into the B–X bond of RBX2 (R = Ph, Mes, N(SiMe3)2; X = Cl, Br), which is followed by the migration of the amidinate...