Cobalt (II)-catalyzed direct C3-selective C–H acyloxylation of indoles with tert-butyl peresters
2018
AbstractA Co(II)-catalyzed direct C3-selective C–H acyloxylation of indoles has been realized with tert-butyl peresters serving as both an acyloxy source and an oxidant. This reaction features highly C3 regioselectivity and good functional group tolerance, which provides a convenient and versatile approach to the construction of valuable 3-acyloxyindoles in moderate to excellent yields.
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