Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host-guest complexation with γ-cyclodextrin
2019
We report the modification of 2-ammonio group at halogenated decaborate ions with a 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.
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