Tubular Metal Organic Frameworks from the Curvature of 2D-honeycombed Metal Coordination

A tubular MOF with adequate active sites is prepared by the bending of metal-coordinated honeycombed frameworks via titration, which shows fast catalytic kinetics with lower catalytic loading for CO2 conversion. The TON is observed as 2300 and the corresponding TOF is firstly achieved up to 173 h-1.