Substitution Électrophile Aliphatique. Mécanisme et Vitesse de la Réaction D'Iododémétallation des Tétraméthyl, Éthyl, nPROPYL, nBUTYL et Allylétains
2010
The reactivity of a series of tetraalkyltins towards iodine has been determinated. The rate equation has been found to be v=k2. SnR4. I2 and the rate constant is not affected by added I-. The reaction is an electrophilic substitution at a saturated carbon atom. The following rate constants have been observed: R=CH3, k2=6,81.m−1. sec−1; R=C2H5, k2=0,8; R=nC3H7, k2=0,1; R=nC4H9, k2=0,04.
The CH3leaving groups.
Tetraallyltin has further been found to react 300 million times faster than tetrapropyltin towards I2. An SE2′ mechanism, free from steric effects, is suggested to explain this very large difference.
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