Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3 + 2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines.

Changgui Zhao,Xingang Xie,Shuangshuang Duan,Huilin Li,Ran Fang,Xuegong She

Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3 + 2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines.

2015

Changgui Zhao
Xingang Xie
Shuangshuang Duan
Huilin Li
Ran Fang
Xuegong She

A facile protocol is developed for the cyclization reaction of ether and amine substrates to form 8- and 9-membered ring products in moderate to good yields.

Keywords:

Ether
Dipole
Cascade reaction
Polymer chemistry
Amine gas treating
Organic chemistry
Intramolecular force
Chemistry
Catalysis

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