Syndiotactic Polystyrene Films with Sulfonated Amorphous Phase and Nanoporous Crystalline Phase

A solid-state sulfonation procedure on syndiotactic polystyrene (s-PS) δ-form films allows an easy and uniform sulfonation of the phenyl rings of the amorphous phase and preserves the nanoporous δ-phase. The high degree of sulfonation of the amorphous phase (up to a molar ratio 2/1 between phenyl rings and sulfonic groups) makes this phase highly hydrophilic, whereas the hydrophobic crystalline phase maintains its guest sorption ability. s-PS films, sulfonated only in the amorphous phase and exhibiting the nanoporous δ-phase, present kinetics of guest sorption from water solutions into the crystalline phase, being markedly higher than those of the corresponding unsulfonated films. For instance, DCE sorption kinetics from 50 ppm aqueous solutions show an unaltered DCE equilibrium uptake (close to 4 wt %) associated with a DCE diffusivity increase of more than 70 times. Moreover, the nanoporous crystalline phase and its sorption ability remain essentially unaffected by water sorption/desorption cycles. The ...