[1,2-bis(diphenylphosphino)ethane]bis-(N,N-dimethyldithiocarbamato)iron(III) tetrafluoroborate
2006
The title compound, [Fe(C3H6NS2)2(C26H24P2)]BF4, contains a six-coordinate iron(III) cationic complex, with two bidentate dimethyldithiocarbamate and one 1,2-bis(diphenylphosphino)ethane ligands, and a disordered tetrafluoroborate anion. The cation possesses a crystallographic twofold rotation axis. The cations assemble in the crystal structure in two-dimensional layers via complementary C—H⋯π(phenyl) interactions with channels occupied by tetrafluorborate anions.
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