Novel [2]rotaxanes based on the recognition of pillar[5]arenes to an alkane functionalized with triazole moieties

Abstract Host–guest complexation between an alkane functionalized with triazole moieties and three pillar[5]arenes was studied. Three pillar[5]arene-based [2]rotaxanes were constructed based on this new recognition motif. The sequence of the yields of these [2]rotaxanes was consistent with the order of association constants between the three corresponding pillar[5]arenes and the alkane. 1 H NMR, electrospray ionization mass spectrometry, and NOESY NMR were employed to characterize these [2]rotaxanes.