Автотермический риформинг метана: часть 1. Влияние состава носителя на физико-химические свойства биметаллического NiPd катализатора
2014
To optimize the catalyst formula for ATP of CH 4 the catalytic activity of NiPd/Ce 0.5Zr 0.5O 2/Al 2O 3 и NiPd/La 2O 3/Ce 0.5Zr 0.5O 2/Al 2O 3 samples was studied at variation of Ce 0.5Zr 0.5O 2 (10-30 wt.%) and La 2O 3 (5-20 wt.%) content in the support. The optimal catalyst composition was established. NiPd/20La 2O 3/10Ce 0.5Zr 0.5O 2/Al 2O 3 catalyst was characterized by stable activity with time on stream and provides an H 2 yield of 65% at conversion of CH 4 of 90-100% and at reaction temperature of 850 oC.
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