Rhodium Catalyzed C–C Bond Cleavage/Coupling of 2-(Azetidin-3-ylidene)Acetates and Analogs

Xuan Yang,Wei-Yu Kong,Jia-Ni Gao,Li Cheng,Nan-Nan Li,Meng Li,Hui-Ting Li,Jun Fan,Jin-Ming Gao,Qin Ouyang,Jian-Bo Xie

Rhodium Catalyzed C–C Bond Cleavage/Coupling of 2-(Azetidin-3-ylidene)Acetates and Analogs

2019

Xuan Yang
Wei-Yu Kong
Jia-Ni Gao
Li Cheng
Nan-Nan Li
Meng Li
Hui-Ting Li
Jun Fan
Jin-Ming Gao
Qin Ouyang
Jian-Bo Xie

The C–C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by rhodium complex was studied, with “conjugate addition / β-C cleavage / protonation” strategy.

Keywords:

Conjugate
Cleavage (embryo)
Protonation
Organic chemistry
Catalysis
Rhodium
Medicinal chemistry
Bond cleavage
Aryl
Chemistry

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