Cholesterol-based dimeric liquid crystals: synthesis, mesomorphic behaviour of frustrated phases and DFT study

Chiral unsymmetrical dimeric liquid crystals consisting of a cholesterol moiety as chiral entity and a substituted salicylidene imine core (with the substituent being butyl or fluoro or chloro group) interconnected through an even methylene spacer have been synthesised and their mesomorphic properties are characterised. All the dimers exhibit enantiotropic mesophases. The butyl homologue exhibited N* phase only, the fluoro- and chloro-substituted compound exhibited frustrated blue phases (BPs), N* phase and SmC* or twisted grain boundary (TGB) phases. The occurrence of a fluid frustrated phase, the BP, in particular, observed in compounds with a polar moiety and bent optimised conformation by density functional theory (DFT) study, indicates the importance of polar structures and bent shape of the compounds. Theoretical calculation was performed in order to study the optimised conformation, polarity and electron density distribution of the synthesised cholesterol derivatives using DFT. Time-dependent densi...