Understanding hydrogen and nitrogen doping on active defects in amorphous In-Ga-Zn-O thin film transistors

This work analyses the physics of active trap states impacted by hydrogen (H) and nitrogen (N) dopings in amorphous In-Ga-Zn-O (a-IGZO) thin-film transistors (TFTs) and investigates their effects on the device performances under back-gate biasing. Based on numerical simulation and interpretation of the device transfer characteristics, it is concluded that the interface and bulk tail states, as well as the 2+ charge states (i.e., acceptors VO2+) related to oxygen vacancy (VO), are neutralized by the H/N dopants incorporation via an experimental plasma treatment. Moreover, the simulation reveals that an acceptor-like defect VOH has been induced by the H doping, to support the observed additional degradation of device subthreshold slope. Superior stability of the optimized a-IGZO TFTs under a proper amount of H/N doping is demonstrated by the decreased density of VO-related defects in simulation, where hole (VO0 donor) and electron trapping (Oi acceptor) occurs during the negative or positive bias stresses. ...